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Kinetic equations for a quantum gas with bound states
Authors:James A. McLennan
Affiliation:(1) Department of Physics, Lehigh University, Building 16, 18015 Bethlehem, Pennsylvania
Abstract:
The kinetic theory for dense gases is modified to take into account the existence of bound states. A molecular chaos condition is used which corresponds to the division of the two- and three-particle Hubert spaces into scattering and boundstate subspaces. A kinetic stage results from a long-time limit which converges to yield time-independent functionals for the two- and three-particle density matrices, as functionals of the density matrices for atoms and molecules. Coupled kinetic equations are obtained which describe the gas as a reacting mixture of atoms and diatomic molecules. These include the effects of scattering and rearrangement collisions between the atom and the molecule, and of molecular formation and dissociation.
Keywords:Kinetic theory  dense gases  bound states  polyatomic gases  reactions
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