Kinetic equations for a quantum gas with bound states |
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Authors: | James A. McLennan |
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Affiliation: | (1) Department of Physics, Lehigh University, Building 16, 18015 Bethlehem, Pennsylvania |
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Abstract: | ![]() The kinetic theory for dense gases is modified to take into account the existence of bound states. A molecular chaos condition is used which corresponds to the division of the two- and three-particle Hubert spaces into scattering and boundstate subspaces. A kinetic stage results from a long-time limit which converges to yield time-independent functionals for the two- and three-particle density matrices, as functionals of the density matrices for atoms and molecules. Coupled kinetic equations are obtained which describe the gas as a reacting mixture of atoms and diatomic molecules. These include the effects of scattering and rearrangement collisions between the atom and the molecule, and of molecular formation and dissociation. |
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Keywords: | Kinetic theory dense gases bound states polyatomic gases reactions |
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