The role of oxygen in catalysis |
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| Authors: | J Haber and E M Serwicka |
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| Institution: | (1) Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek 1, 30-239 Kraków, Poland |
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| Abstract: | Catalytic reactions with oxygen are divided into two groups: electrophilic oxidation proceeding through activation of oxygen, and nucleophilic oxidation in which insertion of nucleophilic oxygen species into previously activated organic molecule occurs. The role of different types of lattice oxygen in the nucleophilic oxygen addition as well as catalyst properties determining the electrophilic pathway are discussed. |
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