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Growth structural,spectral, optical and mechanical studies of gamma bis glycinium oxalate (GBGOx) new NLO single crystal by SEST method
Authors:P. Kalaiselvi  S. Alfred Cecil Raj  N. Vijayan  D. Haranath
Affiliation:1. Department of Physics, St. Joseph''s College, Tiruchirapalli 620 002, India;2. CSIR-National Physical Laboratory, New Delhi 110 012, India
Abstract:
Gamma bis glycinium oxalate (GBGOx) crystal was synthesized and grown by slow evaporation solution technique. The structure of pure GBGOx crystal has been examined by single crystal X-ray diffraction analysis. The confirmation with single crystal XRD reveals that the crystal belongs to monoclinic system with space group C2. The FTIR spectrum was recorded to identify the expected functional groups. UV–vis-spectrum shows the lower cut off wavelength and 80% of transmittance in the UV–vis region. The photoluminescence measurement shows that the material is suitable for photonic devices. Preliminary measurement of green light emission using Kurtz powder technique indicates that their second harmonic generation (SHG) efficiency. The microhardness analysis revealed that the grown crystal belongs to soft material category. The encouraging results show that the GBGOx crystals have great potential applications in optical devices.
Keywords:NLO   SHG   XRD   FTIR   GBGOx
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