| 醋酸钯和苯胂酸协同催化苯甲腈水合制备苯甲酰胺 |
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| 引用本文： | 王涛,林政国,胡长文.醋酸钯和苯胂酸协同催化苯甲腈水合制备苯甲酰胺[J].无机化学学报,2019,35(9):1619-1622. |
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| 作者姓名： | 王涛 林政国 胡长文 |
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| 作者单位： | 北京理工大学化学与化工学院原子分子簇科学教育部重点实验室 |
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| 基金项目： | 国家自然科学基金（No.21671019，21701010）资助项目。 |
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| 摘 要： | 以醋酸钯和苯胂酸(物质的量之比nPd∶nAs=3∶2)作为协同催化剂,用于催化苯甲腈水合制备苯甲酰胺。在不额外添加有机溶剂条件下,利用过量苯甲腈兼做溶剂,该反应获得了99%的高产率和100%的苯甲酰胺选择性以及高达186 mol·kg-1·h-1的时空收率,循环反应5轮未发现明显的活性与选择性的降低,催化剂具有良好的循环使用性能。产物的结晶分离研究结果表明苯甲酰胺在0℃的析出百分比为73%,简单过滤即可收集。
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| 关 键 词： | 苯甲腈 水合反应 酰胺 均相催化 |
| 收稿时间： | 2019/4/30 0:00:00 |
| 修稿时间： | 2019/5/17 0:00:00 |
Preparation of Benzamide by Hydration of Benzonitrile with Palladium Acetate and Phenylarsonic Acid as Synergistic Catalyst |
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| WANG Tao,LIN Zheng-Guo and HU Chang-Wen.Preparation of Benzamide by Hydration of Benzonitrile with Palladium Acetate and Phenylarsonic Acid as Synergistic Catalyst[J].Chinese Journal of Inorganic Chemistry,2019,35(9):1619-1622. |
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| Authors: | WANG Tao LIN Zheng-Guo and HU Chang-Wen |
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| Institution: | School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science, Ministry of Education, Beijing Institute of Technology, Beijing 102488, China,School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science, Ministry of Education, Beijing Institute of Technology, Beijing 102488, China and School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science, Ministry of Education, Beijing Institute of Technology, Beijing 102488, China |
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| Abstract: | |
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| Keywords: | benzonitrile hydration amide homogeneous catalysis |
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