| PdCl42-配离子插层类水滑石的组装及其结构特征 |
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| 引用本文： | 张祥征,李殿卿,蒲 敏,D. G. Evans,段 雪.PdCl42-配离子插层类水滑石的组装及其结构特征[J].无机化学学报,2004,20(3):267-272. |
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| 作者姓名： | 张祥征 李殿卿 蒲 敏 D. G. Evans 段 雪 |
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| 作者单位： | 北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京,100029 |
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| 基金项目： | 国家自然科学基金重点资助项目(No.90306012)。 |
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| 摘 要： | 以Mg0.76Al0.24(OH)2(NO3)0.24·0.32H2O LDHs为前体，由离子交换法实现了层间为含Pd阴离子LDHs的插层组装。用XRD、FT-IR、TG-DTA和ICP等手段对样品进行表征和分析，结果表明Pd以PdCl42-的形式位于层间，反应24 h达到最大插层限度，配离子平面平行于层板排布，3个PdCl42-配离子构成的几何空间的中心存在1个NO3-离子以维持插层结构能量最低。所得插层产物的化学组成式为Mg0.74Al0.26(OH)2(PdCl4)0.11(NO3)0.04·0.62H2O。
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| 关 键 词： | 水滑石 插层 PdCl42-配离子 |
| 修稿时间： | 2003年9月16日 |
Assembly and Structural Characterization of PdCl42--Intercalated LDHs |
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| ZHANG Xiang-Zheng,LI Dian-Qing,PU Min,Evans D. G. and DUAN Xue.Assembly and Structural Characterization of PdCl42--Intercalated LDHs[J].Chinese Journal of Inorganic Chemistry,2004,20(3):267-272. |
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| Authors: | ZHANG Xiang-Zheng LI Dian-Qing PU Min Evans D G and DUAN Xue |
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| Institution: | Key Lab of Science and Technology of Controllable Chemical Reactions, Education Ministry, Beijing University of Chemical Technology, Beijing 100029,Key Lab of Science and Technology of Controllable Chemical Reactions, Education Ministry, Beijing University of Chemical Technology, Beijing 100029,Key Lab of Science and Technology of Controllable Chemical Reactions, Education Ministry, Beijing University of Chemical Technology, Beijing 100029,Key Lab of Science and Technology of Controllable Chemical Reactions, Education Ministry, Beijing University of Chemical Technology, Beijing 100029 and Key Lab of Science and Technology of Controllable Chemical Reactions, Education Ministry, Beijing University of Chemical Technology, Beijing 100029 |
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| Abstract: | |
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| Keywords: | LDHs intercalation PdCl42- complex ion |
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