Copper(II), nickel(II), and zinc(II) complexes with o-tozylaminobenzaldehyde 4,6-dimethylpyrimidyl hydrazone |
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| Authors: | L. D. Popov V. V. Tkachev Yu. P. Tupolova S. A. Borodkin G. V. Shilov E. A. Ugolkova O. I. Askalepova A. S. Burlov V. V. Lukov I. N. Shcherbakov S. I. Levchenkov V. V. Minin |
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| Affiliation: | 1.Southern Federal University,Rostov-on-Don,Russia;2.Institute of Problems of Chemical Physics,Russian Academy of Sciences,Chernogolovka, Moscow oblast,Russia;3.Kurnakov Institute of General and Inorganic Chemistry,Russian Academy of Sciences,Moscow,Russia;4.Institute of Physical and Organic Chemistry,Southern Federal University,Rostov-on-Don,Russia;5.Southern Scientific Center,Russian Academy of Sciences,Rostov-on-Don,Russia |
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| Abstract: | ![]()
o-Tosylaminobenzaldehyde dimethylpyrimidyl hydrazone and its copper(II), nickel(II), and zinc(II) complexesare synthesized and studied. According to the X-ray diffraction data, the zinc(II) complex has the structure of a tetragonal pyramid with the N3O donor ligand environment. According to EPR and magnetochemistry data, the copper(II) complex has a similar structure of the chelate core. In the nickel(II) complex, the solvent molecule completes the coordination core to an octahedron. |
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