Synthesis,structure, and optical properties of iridium(III) complex with 1-benzyl-2-phenylbenzimidazole and 4,4'-dicarboxy-2,2'-bipyridyne |
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Authors: | S. I. Bezzubov A. A. Bilyalova I. V. Kuznetsova K. G. Pavlov Yu. M. Kiselev V. D. Dolzhenko |
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Affiliation: | 1.Kurnakov Institute of General and Inorganic Chemistry,Russian Academy of Sciences,Moscow,Russia;2.Department of Chemistry,Moscow State University,Moscow,Russia |
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Abstract: | A new cyclometalated iridium(III) complex [Ir(L)2(Hdcbpy)] (1) has been synthesized, where L is 1-benzyl-2-phenylbenzimidazole and Hdcbpy is monoprotonated 4,4′-dicarboxy-2,2′-bipyridine. The structure of complex 1 has been determined by X-ray diffraction. The optical properties of complex 1 have been studied, and the quantum yield of luminescence has been measured. |
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