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螺旋链聚甲基丙烯酸三苯甲酯包敷硅胶分离旋光异构体
引用本文:吴晓军,陈传福,任长玉,习复,刘国诠.螺旋链聚甲基丙烯酸三苯甲酯包敷硅胶分离旋光异构体[J].色谱,1995,13(3):190-191.
作者姓名:吴晓军  陈传福  任长玉  习复  刘国诠
作者单位:中国科学院化学研究所
摘    要:用螺旋链聚甲基丙烯酸三苯甲酯(PTrMA)包敷硅胶高效液相色谱法分离了十五对PTH衍生氨基酸和药物旋光异构体,十四对系首次在PTrMA柱上进行分离,其中十三对旋光异构体获得了分离。

关 键 词:高效液相色谱  聚甲基丙烯酸三苯甲酯  旋光异构体分离  

Resolution of Racemic Compounds with Optically Active Poly(Triphenylmethyl Methacrvlate)Column
Wu Xiaojun,Chen Chuanfu,Ren Changyu,Xi Fu and Liu Guoquan.Resolution of Racemic Compounds with Optically Active Poly(Triphenylmethyl Methacrvlate)Column[J].Chinese Journal of Chromatography,1995,13(3):190-191.
Authors:Wu Xiaojun  Chen Chuanfu  Ren Changyu  Xi Fu and Liu Guoquan
Abstract:ptically active poly(triphenylmethyl inethacrylate)(PTrMA)was coated on macroporous silicaspheres silanized with dichlorodiphenylsilane. The resulting stationary phase of high performance liquid chro-matography was used for the resolution of 1 5 kinds of racemic PTH(3-phenyl-2-thiohydantoin) derivatizedamino acids and pharmaceutical comoounds.
Keywords:high performance liquid chromatography  poly(triphenylmethyl methacrylate)  resolution of racemic compounds  
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