C60与环己烷及环己烯离子体系的气相反应 |
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引用本文: | 刘子阳,A郝国仑,郭兴华,刘淑莹.C60与环己烷及环己烯离子体系的气相反应[J].化学学报,1995,53(8):812-815. |
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作者姓名: | 刘子阳 A郝国仑 郭兴华 刘淑莹 |
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作者单位: | 中国科学院长春应用化学研究所 |
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基金项目: | 国家自然科学基金,中国科学院应用谱学开放实验室资助项目 |
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摘 要: | 在气相条件下研究了C60与环己烷及环己烯的离子-分子反应。C60可与上述体系中多种离子发生反应, 生成相应的加合离子, 表现出C60化学性质的活泼性和多样性。C60与C4H7^+和C5H7^+离子反应可能生成2+4]环加成的加合离子。
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关 键 词: | 环己烷 环己烯 气相反应 富勒烯 离子-分子反应 |
Gas-phase reactions of C60 with the ion systems of cyclohexane and cyclohexene |
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Abstract: | The DCI MS of C60 with the reactions of gaseous cyclohexane and cyclohexene have been studied. Several kinds reactions of C60 have been observed. The results show that the gas-phase C60 has very active chemical properties. The adduct ions of C60C4H7]^+ and C60C5H7]^+ may be formed by 2+4] cycloaddition where one of double bonds of C60 acted as dienophilic unit. |
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Keywords: | CYCLOHEXANE CYCLOHEXENE GAS PHASE REACTION FULLERENES |
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