Synthesis and properties of a new member of the calixnaphthalene family: a C(2)-symmetrical endo-calix[4]naphthalene |
| |
| Authors: | Chowdhury Sultan Georghiou Paris E |
| |
| Institution: | Department of Chemistry, Memorial University of Newfoundland, St. John's, Newfoundland and Labrador A1B 3X7, Canada. parisg@mun.ca |
| |
| Abstract: | The synthesis of a new endo-calix4]naphthalene is described. The reaction sequence involves the cyclocondensation of a key bisnaphthylmethane intermediate (8) with formaldehyde. This key intermediate (8) is formed using a modified Suzuki-Miyaura Pd-catalyzed cross-coupling reaction between bromomethylnaphthyl (6) and naphthylboronic acid (7), both of which can be derived from 2-hydroxynaphthoic acid. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
