Synthese und Kristallstruktur von [Fe(MeCN)6][Fe2OCl6] |
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| Authors: | Norbert Kuhn,Heike Kotowski,Cä cilia Maichle-Mö ß mer,Ulrich Abram |
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| Abstract: | Synthesis and Crystal Structure of [Fe(MeCN)6][Fe2OCl6] [Fe(MeCN)6][Fe2OCl6] ( 2 ) is obtained by passing dry air through a solution of FeCl2 in acetonitrile in almost quantitative yield. 2 crystallises in the trigonal space group R 3 [a = b = 12.121(1), c = 29.875(6) Å, Z = 6]. The oxygen atom in the Fe2OCl6 anion occupies the 3 position and causes therefore an Fe–O–Fe angle of 180°. The refinement in the triclinic space group P1 leads to a slightly bent arrangement of the Fe–O–Fe fragment. |
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| Keywords: | Iron complexes crystal structure |
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