Abstract: | The synthesis and crystal structure of a new fluoromanganate(III), (H3N(CH2)2)2NH2]2MnF5(H2O)]3, is reported. The unit cell is unusually large: monoclinic, P21/c (no. 14), a = 41.0512(13) Å; b = 9.6469(4) Å; c = 12.8021(7) Å; β = 91.927(4)°; Z = 8, R = 0.0627 and wR2 = 0.1347. The MnF5(H2O)]2– anions are octahedral with a strong distortion along the F–Mn OH2 axes due to the Jahn-Teller effect. A very rich intermolecular hydrogen bond framework is present, leading to chains of octahedra linked by double-hydrogen bonds. The polarized optical spectra on single crystals are explained in terms of the intraconfigurational d4 transitions split by a ligand field of C4v symmetry. |