| PrP_5O_(14)晶体中Pr~(3+)离子的f-d辐射跃迁 |
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| 引用本文： | 张思远.PrP_5O_(14)晶体中Pr~(3+)离子的f-d辐射跃迁[J].光学学报,1987(10). |
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| 作者姓名： | 张思远 |
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| 作者单位： | 中国科学院长春应用化学研究所 |
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| 摘 要： | 本文讨论了计算稀土离子4f~(N-1)5d-f~N辐射跃迁几率的一般方法,提出了这类跃迁的亲态选择定则。并在C_(2v)群对称下,具体计算了Pr~(3+)离子在PrP_5O_(14)晶体中的f-d辐射跃迁几率,结果指出稀土离子的f-d跃迁几率比f-f跃迁几率大得多。
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| 关 键 词： | 跃迁几率 泡利排斥原理 |
The f-d radiative transition probability of Pr~(3+) in PrP_5O_(14) crystals |
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| ZHANG SIYuAN.The f-d radiative transition probability of Pr~(3+) in PrP_5O_(14) crystals[J].Acta Optica Sinica,1987(10). |
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| Authors: | ZHANG SIYuAN |
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| Abstract: | In this paper, the calculation method of 4fN-15d-fN radiative transition probability is discussed, the parentage selectrive rule is proposed, and the f-d radiative transition probabilities of Pr3+ in PrP5O14 crystals are calculated. The results show that the f-d transition probability of rare earth is much larger than f-f transition. |
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| Keywords: | transition probability Pauli's exclusion principle |
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