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Effect of Impurities on the Etching of Sodium Chloride Crystals
Authors:A. Koziejowska  K. Sangwal
Abstract:The results of a study of the effect of HgCl2, ZnCl2, PbCl2 and CaCl2 on the surface micro-morphology and kinetics of etching of {100} planes of NaCl crystals in methanol and ethanol are described and discussed. It was found that addition of an impurity to the solvent leads to the formation of contrasting dislocation etch pits, and that the overall dissolution rate in a solvent decreases with an increase in additive concentration. In the case of HgCl2 impurity added to methanol terraced etch pits are observed, but their terracing behaviour diminishes with the increasing impurity concentration.
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