Cocrystallization of adamantane‐1,3‐dicarboxylic acid and 4,4′‐bipyridine |
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Authors: | Yue Pan Kunhao Li Wenhua Bi Jing Li |
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Abstract: | The cocrystallization of adamantane‐1,3‐dicarboxylic acid (adc) and 4,4′‐bipyridine (4,4′‐bpy) yields a unique 1:1 cocrystal, C12H16O4·C10H8N2, in the C2/c space group, with half of each molecule in the asymmetric unit. The mid‐point of the central C—C bond of the 4,4′‐bpy molecule rests on a center of inversion, while the adc molecule straddles a twofold rotation axis that passes through two of the adamantyl C atoms. The constituents of this cocrystal are joined by hydrogen bonds, the stronger of which are O—H...N hydrogen bonds O...N = 2.6801 (17) Å] and the weaker of which are C—H...O hydrogen bonds C...O = 3.367 (2) Å]. Alternate adc and 4,4′‐bpy molecules engage in these hydrogen bonds to form zigzag chains. In turn, these chains are linked through π–π interactions along the c axis to generate two‐dimensional layers. These layers are neatly packed into a stable crystalline three‐dimensional form via weak C—H...O hydrogen bonds C...O = 3.2744 (19) Å] and van der Waals attractions. |
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