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Synthesis and Crystal Structure of Dichlorobis(dimethylsulfoxide)oxoperoxo Molybdenum(VI) |
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| Authors: | Heron Vrubel,Manfredo H rner,Estela dos Reis Crespan,Shirley Nakagaki,F bio S. Nunes |
| Abstract: | Hydrogen peroxide reacts with [MoO2Cl2(dmso)2] to produce orange crystals of the title complex, [MoO(O2)Cl2(dmso)2]. The structure is orthorhombic with distorted pentagonal bipyramidal geometry around the molybdenum ion. A short O‐O bond length suggested the presence of a superoxide, but electron paramagnetic resonance measurements definitely supported the peroxo structure. |
| Keywords: | Molybdenum Dimethylsulfoxide Crystal structures |