Hydrosilylation Reactions Catalyzed by Rhenium |
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| Authors: | Duo Wei Ruqaya Buhaibeh Yves Canac Jean-Baptiste Sortais |
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| Institution: | 1.University Rennes, CNRS, ISCR-UMR 6226, 35000 Rennes, France;2.LCC-CNRS, Université de Toulouse, UPS, 31400 Toulouse, France; (R.B.); (Y.C.);3.Institut Universitaire de France 1 rue Descartes, CEDEX 05, 75231 Paris, France |
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| Abstract: | Hydrosilylation is an important process, not only in the silicon industry to produce silicon polymers, but also in fine chemistry. In this review, the development of rhenium-based catalysts for the hydrosilylation of unsaturated bonds in carbonyl-, cyano-, nitro-, carboxylic acid derivatives and alkenes is summarized. Mechanisms of rhenium-catalyzed hydrosilylation are discussed. |
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| Keywords: | rhenium hydrosilylation unsaturated bonds carbonyls alkenes |
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