X-rays and matter – the basic interactions

In this introductory article we attempt to provide the theoretical basis for developing the interaction between X-rays and matter, so that one can unravel properties of matter by interpretation of X-ray experiments on samples. We emphasize that we are dealing with the basics, which means that we shall limit ourselves to a discussion of the interaction of an X-ray photon with an isolated atom, or rather with a single electron in a Hartree–Fock atom. Subsequent articles in this issue deal with more complicated – and interesting – forms of matter encompassing many atoms or molecules. To cite this article: J. Als-Nielsen, C. R. Physique 9 (2008).