Abstract: | In the title compound, poly(2,2′‐bipyridine‐κ2N,N′)manganese(II)]‐μ3‐N‐tosyl‐l ‐glutamato‐κ4O,O′:O′′:O′′′], Mn(tsgluo)(bipy)]n, where tsgluo is N‐tosyl‐l ‐glutamate (C12H13NO6S) and bipy is 2,2′‐bipyridine (C10H8N2), the Mn atoms are octahedrally coordinated by two N atoms of one bipy ligand and by four O atoms of three tsgluo2− anions. The γ‐carboxyl group coordinates to the MnII atom in a chelating mode, while the α‐carboxyl group coordinates in a bidentate–bridging mode. The complex displays a one‐dimensional double‐chain structure. |