Poly[iron(II)‐di‐μ‐imidazole‐4,5‐dicarboxylato‐κ3N3,O4:O5] |
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Authors: | Ying Xu Rui‐Hu Wang Ben‐Yong Lou Lei Han Mao‐Chun Hong |
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Abstract: | In the title compound, Fe(C5H3N2O4)2]n, each Fe atom lies on a centre of symmetry, in an octahedral coordination environment consisting of two chelate rings Fe—N = 2.154 (3) Å and Fe—O = 2.180 (3) Å] and two carboxylate O atoms Fe—O = 2.111 (2) Å] from imidazole‐4,5‐dicarboxylate ligands. Extensive hydrogen‐bonding interactions exist between layers constructed of Fe4 squares, forming tunnels along the a axis with large voids. |
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