Abstract: | Tris(2‐pyridyl)phosphine oxide, (I), C15H12N3OP, is isomorphous with tris(2‐pyridyl)phosphine. Because of a combination of C—H⋯O and C—H⋯N interactions, the crystal packing is denser in the title compound than in the related compounds triphenylphosphine oxide and tris(2‐pyridyl)phosphine. |