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Aqua(2,2′‐di­amino‐4,4′‐bi‐1,3‐thia­zole‐κ2N,N′)(imino­diacetato‐κ3O,N,O′)­chromium(III) chloride mono­hydrate
Authors:Bing‐Xin Liu  Duan‐Jun Xu
Abstract:Crystals of the title compound, Cr(C4H5NO4)(C6H6N4S2)(H2O)]Cl·H2O, consist of CrIII complex cations, Cl counter‐ions and lattice water mol­ecules. The complex cation assumes an octahedral coordination geometry, formed by a tridentate imino­di­acetate dianion (IDA), a di­amino­bi­thia­zole (DABT) mol­ecule and a water mol­ecule. The planar DABT group chelates the CrIII ion with normal Cr—N distances 2.0574 (17) and 2.0598 (17) Å], but the DABT mol­ecule is inclined to the coordination plane by a dihedral angle of 17.23 (7)°. In the monodentate carboxylate groups of the IDA ion, the coordinated C—O bonds 1.288 (3) and 1.284 (3) Å] are much longer than the uncoordinated C—O bonds 1.222 (3) and 1.225 (3) Å].
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