Aqua(2,2′‐diamino‐4,4′‐bi‐1,3‐thiazole‐κ2N,N′)(iminodiacetato‐κ3O,N,O′)chromium(III) chloride monohydrate |
| |
Authors: | Bing‐Xin Liu Duan‐Jun Xu |
| |
Abstract: | Crystals of the title compound, Cr(C4H5NO4)(C6H6N4S2)(H2O)]Cl·H2O, consist of CrIII complex cations, Cl− counter‐ions and lattice water molecules. The complex cation assumes an octahedral coordination geometry, formed by a tridentate iminodiacetate dianion (IDA), a diaminobithiazole (DABT) molecule and a water molecule. The planar DABT group chelates the CrIII ion with normal Cr—N distances 2.0574 (17) and 2.0598 (17) Å], but the DABT molecule is inclined to the coordination plane by a dihedral angle of 17.23 (7)°. In the monodentate carboxylate groups of the IDA ion, the coordinated C—O bonds 1.288 (3) and 1.284 (3) Å] are much longer than the uncoordinated C—O bonds 1.222 (3) and 1.225 (3) Å]. |
| |
Keywords: | |
|
|