Abstract: | The title complex, Ag(C7H5O2)(C4H5N3)]n, is a polymer based on a mononuclear silver(I)‐centered fragment. The AgI atom is trigonally coordinated by two N atoms from two 2‐aminopyrimidine ligands and one O atom from one benzoate anion, giving zigzag polymeric chains with an –Ag—N—C—N–]n backbone running along the a axis. It is proposed that intermolecular hydrogen bonding drives the formation of the chain polymer. |