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Luminescence Determination of Europium in High-Purity Yttrium and Gadolinium Oxides
Abstract:ABSTRACT

A luminescence spectrometric method was developed for the determination of ultratrace amounts of europium (down to 1×10?10 M) in high-purity yttrium and gadolinium oxides. This is based on the enhanced luminescence of europium thenoyltrifluoroacetone (TTA)-Tri-n-octyl phosphine oxide (TOPO)-Triton X-100 in the presence of terbium. The luminescence intensity is linear with europium concentration in the range 1×10?9 to 1×10?6 M under the recommended conditions. The optimized procedure is successfully utilized for the determination of ultratrace amounts of europium in yttrium and gadolinum oxides.
Keywords:Europium  Luminescence  TTA  TOPO  Rare earth oxides
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