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Continuous Determination of Free Cyanide by Means of Membrane Diffusion of Gaseous HCN and An Electrode Indicator Technique
Abstract:Abstract

A continuous measurement system for free cyanide has been developed based on the principle of diffusion across a gas-permeable membrane to affect the separation of hydrogen cyanide from the acidified sample solution. The cyanide absorbed in the alkaline indicator solution is subsequently analyzed by an indirect technique using a silver ion-selective electrode. In the concentration range of 30 to 400 μg CN?/L, the accuracy and precision of this method is approximately two percent. The detection limit of this system is approximately 0.5 μg CN?/L.
Keywords:cyanide  cyanide analyzer  gas dialysis  ion-selective electrode  silver cyanide indicator  silver electrode  
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