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Persistent (amino)(silyl)carbenes
Authors:Canac Yves  Conejero Salvador  Donnadieu Bruno  Schoeller Wolfgand W  Bertrand Guy
Institution:UCR-CNRS Joint Research Chemistry Laboratory (UMR 2282), Department of Chemistry, University of California, Riverside, 92521-0403, USA.
Abstract:(Amino)(silyl)carbenes, prepared by substitution reactions at a carbene center, can survive several days at 0 degrees C. These species are not push-pull carbenes as their phosphino analogues and therefore are excellent ligands for transition-metal centers.
Keywords:
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