| 具有麝香香气分子的结构特征及其嗅觉模型 |
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| 引用本文： | 刘靖疆,唐继卫,朱能垂,朱敏慧,范小玲.具有麝香香气分子的结构特征及其嗅觉模型[J].物理化学学报,1992,8(6):799-803. |
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| 作者姓名： | 刘靖疆 唐继卫 朱能垂 朱敏慧 范小玲 |
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| 作者单位： | Department of Chemistry, Tianjin 300071; The Institute of Electronics of Academia Sinica, Beijing 100080 |
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| 摘 要： | 到目前为止,已发现许多分子具有麝香香气,这些分子在组成和结构上似乎很少有相似之处.化合物1-7就是分属几种结构类型的麝香香气分子。
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| 关 键 词： | 麝香的分子结构 嗅觉的分子作用模型 分子力学 |
| 收稿时间： | 1991-05-08 |
| 修稿时间： | 1991-12-22 |
THE STRUCTURAL CHARACTER OF MUSK ODOR MOLECULES AND ITS MODEL OF OLFACTION |
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| Liu Jingjiang,Tang Jiwei,Zhu Nengchui.THE STRUCTURAL CHARACTER OF MUSK ODOR MOLECULES AND ITS MODEL OF OLFACTION[J].Acta Physico-Chimica Sinica,1992,8(6):799-803. |
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| Authors: | Liu Jingjiang Tang Jiwei Zhu Nengchui |
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| Institution: | Department of Chemistry, Tianjin 300071; The Institute of Electronics of Academia Sinica, Beijing 100080 |
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| Abstract: | Molecular interaction model of olfaction for musk odorants are proposed on thebasis of grometric optimization by molecular mechanics. We supose the molecules ofmusk odorants are composed by three parts: fixing groups (polar groups, oxygen forexample, make fixation of odorant molecule); reacting groups (react with the surfaceof lipid bilayer, give the signal of odor); supporting groups (noble to olfaction,their contribution is putting the reacting groups on the suitable positions). The areaof polygon formed by the reacting and fixing groups (accounted with C and O atoms)is about 50A~2. Because supporting groups are noble to olfaction, so that it is rea-sonable, molecules belong to different classes (aliphatic cycles, aromatic cycles,singlecycles, poly-cycles) can have the same musk odor. |
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| Keywords: | Molecular structure of musk ordorant Molecular reaction model of olfaction Molecular mechanics |
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