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| 水中取代水杨醛和氰乙酸酯的反应研究 | |
| 引用本文： | 王香善,曾兆森,李玉玲,史达清,屠树江,魏贤勇,宗志敏. 水中取代水杨醛和氰乙酸酯的反应研究[J]. 有机化学, 2006, 26(10): 1379-1383 |
| 作者姓名： | 王香善 曾兆森 李玉玲 史达清 屠树江 魏贤勇 宗志敏 |
| 作者单位： | 1. 徐州师范大学化学系,徐州,221116;中国矿业大学化学工程学院,徐州,221008;江苏省药用植物生物技术重点实验室,徐州,221116 2. 徐州师范大学化学系,徐州,221116 3. 徐州师范大学化学系,徐州,221116;江苏省药用植物生物技术重点实验室,徐州,221116 4. 中国矿业大学化学工程学院,徐州,221008 |
| 基金项目： | 江苏省高校自然科学基金(No.04KJB150139)资助项目. |
| 摘 要： | 以水杨醛和氰乙酸酯为原料, 以水为溶剂, 以三乙基苄基氯化铵为催化剂在不同的反应温度下合成了两个系列的色烯衍生物, 该方法具有反应条件温和、立体选择性好、产率高等优点. |
| 关 键 词： | 色烯 水杨醛 氰乙酸酯 三乙基苄基氯化铵 水 合成 |
| 收稿时间： | 2005-10-19 |
| 修稿时间： | 2006-04-04 |
Study on the Reaction of Substituted Salicylaldehydes with Cyanoacetate in Water |
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| WANG, Xiang-Shan,ZENG, Zhao-Sen,LI, Yu-Ling,SHI, Da-Qing,TU, Shu-Jiang,WEI, Xian-Yong,ZONG, Zhi-Min. Study on the Reaction of Substituted Salicylaldehydes with Cyanoacetate in Water[J]. Chinese Journal of Organic Chemistry, 2006, 26(10): 1379-1383 | |
| Authors: | WANG Xiang-Shan ZENG Zhao-Sen LI Yu-Ling SHI Da-Qing TU Shu-Jiang WEI Xian-Yong ZONG Zhi-Min |
| Affiliation: | 1. Department of Chemistry, Xuzhou Normal University, Xuzhou 221116;2. School of Chemical Engineering, China University of Mining and Technology, Xuzhou 221008;3. Key Laboratory of Biotechnology on Medical Plant of Jiangsu Province, Xuzhou 221116 |
| Abstract: | Two series of chromene derivatives were synthesized from the substituted salicylaldehyde with cyanoacetate in water at two reaction temperatures catalyzed by triethylbenzyl ammonium chloride (TE-BAC). Such method has the advantages of easier work-up, milder reaction conditions, better yields than other synthetic methods. |
| Keywords: | chromene salicylaldehyde cyanoacetate triethylbenzyl ammonium chloride water synthesis |
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