Kinetik und Mechanismus des Ligandentausches zwischen Thallium(III)oxinat und Eisen(III) in Propylencarbonat |
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| Authors: | Rudolf W Soukup Valentin N Sapunov Hossein Ateshykashi Roland Schmid |
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| Institution: | (1) Institut für Anorganische Chemie, Technische Universität Wien, A-1060 Wien, Österreich;(2) Chemisch-Technologisches Mendeleev-Institut, Moskau, UdSSR |
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| Abstract: | The transfer of oxinate ions from thallium (III)oxinate to trivalent Fe(DMF)
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in propylenecarbonate takes place via rearrangements within a rapidly formed binuclear thallium(III)—iron(III) complex. In a last rapid step this rearranged complex reacts with excess reactants to the final products whose composition accordingly depends on the ratio of the reactant concentrations. |
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| Keywords: | Kinetics Ligand-transfer Thallium (III) |
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