Anthracene cycloadducts as highly selective chiral auxiliaries |
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| Authors: | Liu Xiang Snyder John K |
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| Affiliation: | Boston University, Department of Chemistry, Boston, MA 02215, USA. |
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| Abstract: | A new chiral auxiliary was designed and easily prepared from a Diels-Alder cycloadduct of an enantiomerically pure anthracene with maleimide. Excellent diastereoselectivities in Diels-Alder reactions, conjugate additions, and aldol reactions employing these auxiliaries are now reported. |
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