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Linear-Dendritic Block Copolymers Based on <Emphasis Type="Italic">N</Emphasis>-Isopropylacrylamide and Perfluorinated Polyphenylenegermane: Synthesis and Properties at Various Interfacial Boundaries
Authors:O G Zamyshlyayeva  E A Smirnov  N S Zakharycheva
Institution:1.National Research Nizhny Novgorod State University,Nizhny Novgorod,Russia;2.Research Institute of Chemistry,National Research Nizhny Novgorod State University,Nizhny Novgorod,Russia
Abstract:It is shown that linear-dendritic block copolymers poly(N-isopropylacrylamide)–block–polyphenylenegermane can be prepared by the polymerization of N-isopropylacrylamide in the presence of bis(pentafluorophenyl)germane followed by activated polycondensation with tris(pentafluorophenyl)germane. The properties of the dilute solutions and Langmuir monolayers of the functional polymers and the linear-dendritic block copolymers of N-isopropylacrylamide are studied.
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