Catalytic direct 1,4-conjugate addition of aldehydes to vinylketones on secondary-amines immobilised in FSM-16 silica |
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| Authors: | Shimizu Ken-ichi Suzuki Hiromasa Hayashi Eidai Kodama Tatsuya Tsuchiya Yoshimi Hagiwara Hisahiro Kitayama Yoshie |
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| Institution: | Graduate School of Science and Technology, Niigata University, Ikarashi-2, Niigata 950-2181, Japan. |
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| Abstract: | Direct 1,4-conjugate addition of naked aldehydes to vinylketones is catalysed effectively by N-methyl-3-aminopropylated FSM-16 mesoporous silica, which can be regarded as a novel heterogeneous catalysis for a practical C-C bond formation reaction. |
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