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铂沉积对Ga2O3-SiO2纳米粒子光催化性能的提高(英文)
作者姓名:E.S.BAEISSA  R.M.MOHAMED
作者单位:a Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box: 80203, Jeddah 21589, Saudi Arabia;
b Advanced Materials Department, Central Metallurgical R&;D Institute, CMRDI, P.O. Box 87, Helwan, Cairo, Egypt;
c Center of Excellence in Environmental Studies, King Abdulaziz University, P.O. Box 80216, Jeddah 21589, Saudi Arabia
基金项目:funded by the Deanship of Scientific Research (DSR), King Abdulaziz University, Jeddah, under grant number (247‐002‐D1433)
摘    要:Ga2O3‐SiO2 nanoparticles were prepared by a sol‐gel method and Pt was then immobilized on their surface via photo‐assisted deposition (PAD). The produced samples were characterized using X‐ray diffraction (XRD), ultraviolet and visible spectroscopy, photoluminescence emission spectroscopy, and surface area measurements. The catalytic performances of the Ga2O3‐SiO2 and Pt/ Ga2O3‐SiO2 samples were evaluated for the degradation of cyanide using visible light. XRD and EDX results showed that the Pt was well dispersed within the Ga2O3‐SiO2 phase and was detected on the surface of the catalyst, which confirmed the successful loading of Pt ions by the PAD method. BET results revealed that the surface area of Ga2O3‐SiO2 was higher than that of Pt/Ga2O3‐SiO2 . 0.3 wt% Pt/Ga2O3‐SiO2 exhibited the highest photocatalytic activity for degradation of cyanide under visible light. The catalyst could be reused with no loss in activity for the first 10 cycles.

关 键 词:Gallic  oxide  Silica  Visible  light  Cyanide  removal
收稿时间:2012-12-06

Enhancement of photocatalytic properties of Ga2O3-SiO2 nanoparticles by Pt deposition
E.S.BAEISSA,R.M.MOHAMED.Enhancement of photocatalytic properties of Ga2O3-SiO2 nanoparticles by Pt deposition[J].Chinese Journal of Catalysis,2013,34(6):1167-1172.
Authors:E S BAEISSA  R M MOHAMED
Institution:a Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box: 80203, Jeddah 21589, Saudi Arabia;
b Advanced Materials Department, Central Metallurgical R&;D Institute, CMRDI, P.O. Box 87, Helwan, Cairo, Egypt;
c Center of Excellence in Environmental Studies, King Abdulaziz University, P.O. Box 80216, Jeddah 21589, Saudi Arabia
Abstract:Ga2O3-SiO2 nanoparticles were prepared by a sol-gel method and Pt was then immobilized on their surface via photo-assisted deposition (PAD). The produced samples were characterized using X-ray diffraction (XRD), ultraviolet and visible spectroscopy, photoluminescence emission spectroscopy, and surface area measurements. The catalytic performances of the Ga2O3-SiO2 and Pt/ Ga2O3-SiO2 samples were evaluated for the degradation of cyanide using visible light. XRD and EDX results showed that the Pt was well dispersed within the Ga2O3-SiO2 phase and was detected on the surface of the catalyst, which confirmed the successful loading of Pt ions by the PAD method. BET results revealed that the surface area of Ga2O3-SiO2 was higher than that of Pt/Ga2O3-SiO2. 0.3 wt% Pt/Ga2O3-SiO2 exhibited the highest photocatalytic activity for degradation of cyanide under visible light. The catalyst could be reused with no loss in activity for the first 10 cycles.
Keywords:Gallic oxide  Silica  Visible light  Cyanide removal
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