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X-ray spectroscopic study of the electronic structure of visible-light responsive N-, C- and S-doped TiO2
Authors:Xiaobo Chen  Per-Anders Glans  Xiaofeng Qiu  Smita Dayal  Wayne D. Jennings  Kevin E. Smith  Clemens Burda  Jinghua Guo
Affiliation:1. Center for Chemical Dynamics & Nanomaterials Research, Department of Chemistry, Case Western Reserve University, Cleveland, OH 44106, USA;2. Department of Physics, Boston University, Boston, MA 02215, USA;3. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA;4. Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, OH 44106, USA
Abstract:The electronic origins of the visible-light response of N-, C- and S-doped TiO2 have been studied using X-ray absorption, X-ray emission, and X-ray photoelectron spectroscopies. New electronic states are observed in the bulk band gap, above the valence band edge of pure TiO2, which can be directly related to the visible-light absorption of the N-, C- and S-doped TiO2 materials.
Keywords:Electronic structure   Doped TiO2   X-ray absorption   X-ray emission   X-ray photoelectron
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