Abstract: | The title compound(E)-2-(4-tert-butyl-5-(4-methoxybenzyl)thiazol-2-ylimino)me-thylphenol was synthesized by the reaction of 5-(4-methoxybenzyl)-4-tert-butylthiazol-2-amine with salicylaldehyde,and its crystal structure was determined by single-crystal X-ray diffraction.The crystal belongs to the monoclinic system,space group P21/c with a=5.9362(8),b=11.5070(15),c=29.460(4),β=97.326(3)°,V=1995.9(5)3,Z=4,F(000)=808,C22H24N2O2S,Mr=380.49,Dc=1.266 g/cm3,S=1.031,μ=0.181 mm--1,the final R=0.0474 and wR=0.1441 for 4327 observed reflections(I > 2σ(I)).Intramolecular O-H…N hydrogen bond is observed in the crystal.The preliminary bioassay showed that the title compound exhibits 95% inhibition rate against Rhizoctonia solani at the test concentration of 500 mg/L. |