| 全固态锂离子选择性电极研究 |
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| 引用本文： | 窦天军,刘妙根,魏世根.全固态锂离子选择性电极研究[J].理化检验(化学分册),2002,38(11):568-570. |
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| 作者姓名： | 窦天军 刘妙根 魏世根 |
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| 作者单位： | 中国工程物理研究院,绵阳,621900 |
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| 摘 要： | 研究了新型载体HPMBP-TOPO体系几种全固态锂离子选择性电极（涂丝电极、单层全固态电极、聚吡咯修饰层内接触电极）的性能。与传统型电极相比，固态电极响应斜率有所降低，而选择性稍有提高。其中聚吡咯修饰层内接触电极性能为最佳，该电极响应斜率为56.7mV/decade，并具有良好再现性和长期稳定性。
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| 关 键 词： | 全固态锂离子选择性电极 电极响应斜率 性能 HPMBP－TOPO体系 |
| 文章编号： | 1001-4020(2002)11-0568-03 |
| 修稿时间： | 2001年1月15日 |
STUDY ON ALL-SOLID STATE LITHIUM ION SELECTIVE ELECTRODES |
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| DOU Tian jun,LIU Miao gen,WEI Shi gen.STUDY ON ALL-SOLID STATE LITHIUM ION SELECTIVE ELECTRODES[J].Physical Testing and Chemical Analysis Part B:Chemical Analgsis,2002,38(11):568-570. |
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| Authors: | DOU Tian jun LIU Miao gen WEI Shi gen |
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| Abstract: | Several solid state lithium ion selective electrodes with new type carriers (coated wire electrode CWE, single piece solid state electrode SPE, solid contact ion selective electrode SCISE) were studied in the paper. The slope values of solid state electrodes were found to be lower than that of the conventional electrode. But the selectivity was improved. The best one was SCISE modified with poly pyrrole. The electrode was of good reproducibility and long term stability with a slope of 56.7mV/decade. |
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| Keywords: | Lithium Solid state ion Selective electrode |
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