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Study of size-dependent glass transition and Kauzmann temperature of titanium dioxide nanoparticles
Authors:Shree Mishra  Prafulla K. Jha  Arun Pratap
Affiliation:(1) Department of Physics, Bhavnagar University, Bhavnagar, 364022, India;(2) Faculty of Technology and Engineering, Applied Physics Department, The M. S. University of Baroda, Vadodara, 390001, India
Abstract:In this article, we have studied the size effect on glass transition and Kauzmann temperature of spherical TiO2 nanoparticles using Arrhenius relation and Lindemann’s criteria under their dynamic limit. The melting point of nanoparticles decreases with decrease in size of the nanoparticles. The glass transition temperature and Kauzmann temperature are analyzed through the size effect on the melting temperature. The glass transition and Kauzmann temperatures decrease with the decrease in size of TiO2 nanoparticles.
Keywords:
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