Pd(0)-catalyzed diarylation of sp3 C-H bond in (2-azaaryl)methanes |
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| Authors: | Song Guoyong Su Yan Gong Xue Han Keli Li Xingwei |
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| Affiliation: | Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road, Dalian 116023, China. |
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| Abstract: | A highly efficient and selective palladium-catalyzed diarylation of (2-azaaryl)methanes at the methyl group is described. Aryl chlorides proved reactive enough. A palladium η(3)-azaallyl intermediate has been identified on the basis of DFT studies. |
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