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Highly efficient synthesis of homoallylic alcohols and amines via allylation of aldehydes and imines catalyzed by ZrOCl2·8H2O in water
Authors:Wei Shen  Jian-Jun Feng
Affiliation:Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, People’s Republic of China
Abstract:The allylation of aldehydes and imines has efficiently been carried out by treatment with allyltributylstannane in the presence of a catalytic amount of ZrOCl2·8H2O in water to form the corresponding homoallylic alcohols and amines, respectively, in high yields.
Keywords:Allylation   Allyltin   ZrOCl2·  8H2O   Water as solvent
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