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Supramolecular polymers formed by cinnamoyl cyclodextrins |
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| Authors: | Akira Harada Masahiko Miyauchi Taiki Hoshino |
| Affiliation: | Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan |
| Abstract: | 6-Cinnamoyl α-cyclodextrin (6-CiO-α-CD) and 6-cinnamoyl β-cyclodextrin (6-CiO-β-CD) were prepared. 6-CiO-α-CD formed intermolecular complexes to give supramolecular oligomers. 6-CiO-β-CD formed insoluble supramolecular complexes in the solid state. The structures of these complexes are discussed. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3519–3523, 2003 |
| Keywords: | supramolecular polymer cyclodextrin inclusion complex host-guest interaction two-dimensional (2D) NMR vapor pressure osmometry host-quest system inclusion chemistry molecular recognition |