| 四卤化碳: 强碱反应体系顺磁共振研究 |
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| 引用本文： | 陈士明,葛明陶,郭时清,许临晓,陶凤岗.四卤化碳: 强碱反应体系顺磁共振研究[J].有机化学,1990,10(1):74-77. |
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| 作者姓名： | 陈士明 葛明陶 郭时清 许临晓 陶凤岗 |
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| 作者单位： | 复旦大学分析测试中心，复旦大学分析测试中心，复旦大学分析测试中心，复旦大学化学系，复旦大学化学系 上海，200433，上海，200433，上海，200433，上海，200433，上海，200433 |
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| 摘 要： | 单电子转移反应是物理有机化学中十分活跃的研究领域之一,现已发现许多有机反应中都存在着单电子转移过程。探讨不同的单电子转移反应体系,了解其中电子给、受体之间的相互作用,不仅对深入了解反应机理有理论
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| 关 键 词： | 四卤化碳 单电子转移 游离基 ESR谱 |
ESR Study on the Reaction System of Carbon Tetrahalide with Strong Bases |
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| CHEN Shi-Ming,GE Ming-Tao,GUO Shi-Qing,XU Lin-Xiao,TAO Feng-Gang Centre of Analysis and Measurement,Fudan University,Shanghai Deparfment of Chemistry,Fudan University,Shanghai.ESR Study on the Reaction System of Carbon Tetrahalide with Strong Bases[J].Chinese Journal of Organic Chemistry,1990,10(1):74-77. |
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| Authors: | CHEN Shi-Ming GE Ming-Tao GUO Shi-Qing XU Lin-Xiao TAO Feng-Gang Centre of Analysis and Measurement Fudan University Shanghai Deparfment of Chemistry Fudan University Shanghai |
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| Institution: | CHEN Shi-Ming,GE Ming-Tao,GUO Shi-Qing,XU Lin-Xiao,TAO Feng-Gang Centre of Analysis and Measurement,Fudan University,Shanghai 200433 Deparfment of Chemistry,Fudan University,Shanghai 200433 |
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| Abstract: | The rcaction systems of carbon tetrahalide with potassium hydroxide (sodiumethoxide) was studied by ESR. It was found by the spin trapping that the trihalomethylradical was formed in the reaction systems. A single electron transfer (SET) mechanism wassuggested in this paper. |
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| Keywords: | free radical electron spin resonance (ESR) spin trapping single electron transfer (SET) carbon tetrahalide |
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