Absolute frequencies of CO2 laser transitions by multiplication of CO2 laser difference frequencies

Frequencies of CO₂ laser transitions have been compared to the Cs standard by a four-step frequency chain using difference-frequencies from five CO₂ isotope lasers. A tungsten-nickel diode generates the differences and their harmonics. Measurement of the 10.71 μm R(6) transition of ¹³C¹⁸O₂ is described. The absolute frequency was found to be 27 979 469.512(65) MHz. Simultaneously, the four other CO₂ frequencies in the chain were also determined.