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Three-component catalytic method for synthesis of α-amino phosphonates with the use of α-amino acids as amine component |
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| Authors: | E D Matveeva T A Podrugina M V Prisyazhnoi I N Rusetskaya N S Zefirov |
| Institution: | (1) Chemistry Department, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992 Moscow, Russian Federation |
| Abstract: | Interaction of aliphatic and aromatic aldehydes and ketones with optically active L-α-amino acids or their esters in the three-component catalytic one-pot synthesis of α-aminophosphonates was studied. The corresponding α-amino phosphonates are formed in high yields as mixtures of diastereomers. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 768–774, April, 2007. |
| Keywords: | α -amino phosphonates the Kabachnick-Fields reaction phthalocyanines aluminum chloride glycine alanine phenylalanine α -amino acids carbonyl compounds |
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