A novel synthesis of α-hydroxy- and α,α′-dihydroxyketone from α-iodo and α,α′-diiodo ketone using photoirradiation |
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| Authors: | CAkira Horiuchi Akinori Takeda Wen Chai Kishoh Ohwada Shun-Jun Ji TTomoyoshi Takahashi |
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| Institution: | aDepartment of Chemistry, Rikkyo (St. Paul's) University, Nishi-Ikebukuro, Toshima-Ku, Tokyo 171-8501, Japan;bDepartment of Chemistry and Chemical Engineering, Suzhou University, 1 Shizi St. Suzhou, Jiangsu 215006, PR China;cDepartment of Chemistry, The Jikei University School of Medicine, Kokuryo-cho, Chofu-shi, Tokyo 182-8570, Japan |
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| Abstract: | A novel reaction of α-iodo ketone (α-iodocycloalkanone, α-iodo-β-alkoxy ester, and α-iodoacyclicketone) with irradiation under a high-pressure mercury lamp gave the corresponding α-hydroxyketone in good yields. In the case of α,α′-diiodo ketone, α,α′-dihydroxyketone which little has been reported until now was obtained. This reaction affords a new, clean and convenient synthetic method for α-hydroxy- and α,α′-dihydroxyketone. |
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