Self‐Healing,Expansion–Contraction,and Shape‐Memory Properties of a Preorganized Supramolecular Hydrogel through Host–Guest Interactions |
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Authors: | Kohei Miyamae Masaki Nakahata Yoshinori Takashima Akira Harada |
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Abstract: | Supramolecular materials cross‐linked between polymer chains by noncovalent bonds have the potential to provide dynamic functions that are not produced by covalently cross‐linked polymeric materials. We focused on the formation of supramolecular polymeric materials through host–guest interactions: a powerful method for the creation of nonconventional materials. We employed two different kinds of host–guest inclusion complexes of β‐cyclodextrin (βCD) with adamantane (Ad) and ferrocene (Fc) to bind polymers together to form a supramolecular hydrogel (βCD‐Ad‐Fc gel). The βCD‐Ad‐Fc gel showed self‐healing ability when damaged and responded to redox stimuli by expansion or contraction. Moreover, the βCD‐Ad‐Fc gel showed a redox‐responsive shape‐morphing effect. We thus succeeded in deriving three functions from the introduction of two kinds of functional units into a supramolecular material. |
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Keywords: | Formgedä chtnis Kü nstliche Muskeln Selbstheilung Supramolekulare Gele Wirt‐Gast‐Systeme |
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