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V2Ga5的晶体结构
引用本文:陆学善,梁敬魁.V2Ga5的晶体结构[J].物理学报,1965,21(5):997-1007.
作者姓名:陆学善  梁敬魁
作者单位:中国科学院;中国科学院
摘    要:本文利用单晶与粉末衍射方法测定了V2Ga5的晶体结构。V2Ga5属四方晶系,其单相区约为VGa2—V2Ga5。在18℃的点阵常数是a=8.9540?,c=2.6892?,每个晶胞含有二个化合式量,空间羣为D4h5—P4/mbm。V原子与Ga原子分别占据在4(h)与8(i),2(d)的等效位置上。参数为:x
收稿时间:6/9/1964 12:00:00 AM

THE CRYSTAL STRUCTURE OF V2Ga5
LU HSUEH-SHAN and LIANG CHING-KWEI.THE CRYSTAL STRUCTURE OF V2Ga5[J].Acta Physica Sinica,1965,21(5):997-1007.
Authors:LU HSUEH-SHAN and LIANG CHING-KWEI
Abstract:The crystal structure of V2Ga5 has been determined by the method of X-ray diffraction from single crystal oscillation photographs and Debye-Scherrer photographs. The homogeneity range of this phase in the V-Ga system extends approximately from VGa2 to V2Ga5. The crystal belongs to the tetragonal system, the lattice spacings at 18℃ being a = 8.9540? and c = 2.6892?. There are two formula units per unit cell. The space group is D4h5-P4/mbm. The four V atoms are situated at the 4(h) positions, while the ten Ga atoms are situated at the 8(i) and 2(d) positions, with xh= 0.180, xi= 0.070, and yi= 0.210.
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