Addition to electron deficient olefins of alpha-oxy carbon- centered radicals, generated from cyclic ethers and acetals by the reaction with alkylperoxy- lambda(3)-iodane |
| |
| Authors: | Sueda Takuya Takeuchi Yasunori Suefuji Takashi Ochiai Masahito |
| |
| Affiliation: | Faculty of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan. |
| |
| Abstract: | ![]()
Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 degrees C generates alpha-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
