| 金属离子对苯甲酰丙酮选择性还原的影响 |
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| 引用本文： | 黄燕敏,崔建国,刘红星,吴玉娟.金属离子对苯甲酰丙酮选择性还原的影响[J].合成化学,2005,13(5):458-460. |
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| 作者姓名： | 黄燕敏 崔建国 刘红星 吴玉娟 |
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| 作者单位： | 广西师范学院,化学系,广西,南宁,530001;广西师范学院,化学系,广西,南宁,530001;广西师范学院,化学系,广西,南宁,530001;广西师范学院,化学系,广西,南宁,530001 |
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| 基金项目： | 广西自然科学基金资助项目（0135011）;广西教育厅科学基金资助项目 |
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| 摘 要： | 以NaBH4为还原剂，研究了金属离子对苯甲酰丙酮选择性还原的影响。结果发现，添加Cd^2＋主要得到3-羰基被还原的产物，而单独使用硼氢化钠还原时却得到两个羰基同时被还原的产物。
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| 关 键 词： | NaBH4 选择性还原 苯甲酰丙酮 金属离子 |
| 文章编号： | 1005-1511（2005）05-0458-03 |
| 收稿时间： | 2004-07-08 |
| 修稿时间： | 2004-09-09 |
Effect of Some Metal Ions on Selective Reduction of Benzoyl Acetone |
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| HUANG Yan-min,CUI Jian-guo,LIU Hong-xing,WU Yu-juan.Effect of Some Metal Ions on Selective Reduction of Benzoyl Acetone[J].Chinese Journal of Synthetic Chemistry,2005,13(5):458-460. |
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| Authors: | HUANG Yan-min CUI Jian-guo LIU Hong-xing WU Yu-juan |
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| Institution: | Department of Chemistry, Guangxi Normal College, Nanning 530001, China |
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| Abstract: | Effect of some metal ions on selective reduction of benzoyl acetone was investigated(using) NaBH_4 as a reducer.The results showed that 3-carbonyl was reduced with Cd~(2~+) addition,and 1,3-dicarbonyl were reduced without additive. |
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| Keywords: | NaBH4 selective reduction benzoyl acetone metal ion |
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