Self‐Assembled Fibers Containing Stable Organic Radical Moieties: Alignment and Magnetic Properties in Liquid Crystals |
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| Authors: | Hiroki Eimura Yoshikazu Umeta Prof. Dr. Hiroko Tokoro Prof. Dr. Masafumi Yoshio Prof. Dr. Shin‐ichi Ohkoshi Prof. Dr. Takashi Kato |
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| Affiliation: | 1. Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo, Hongo, Tokyo, Japan;2. Department of Chemistry, Graduate School of Science, The University of Tokyo, Tokyo, Japan;3. Division of Materials Science Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Japan |
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| Abstract: | Macroscopically oriented stable organic radicals have been obtained by using a liquid–crystalline (LC) gel composed of an l ‐isoleucine‐based low molecular weight gelator containing a 2,2,6,6‐tetramethylpiperidine 1‐oxyl moiety. The LC gel has allowed magnetic measurements of the oriented organic radical. The gelator has formed fibrous aggregates in liquid crystals via intermolecular hydrogen bonds. The fibrous aggregates of the radical gelator are formed and oriented on cooling by applying a magnetic field to the mixture of liquid crystals and the gelator. Superconducting quantum interference device (SQUID) measurements have revealed that both oriented and nonoriented fibrous aggregates exhibited antiferromagnetic interactions, in which super‐exchange interaction constant J is estimated as ?0.89 cm?1. |
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| Keywords: | gels liquid crystals magnetic properties radicals self-assembly |
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