N=N bond cleavage by a low-coordinate ironII hydride complex |
| |
| Authors: | Smith Jeremy M Lachicotte Rene J Holland Patrick L |
| |
| Institution: | Department of Chemistry, University of Rochester, Rochester, New York 14627, USA. |
| |
| Abstract: | Reaction of the three-coordinate complex LFeCl (L = bulky beta-diketiminate) with KBEt3H gives a dark red iron(II) hydride complex. The complex is a dimer in the solid state, but spectroscopy and kinetics suggest that an orange three-coordinate monomer is in equilibrium with the dimer in solution. The double bond of azobenzene is completely cleaved by heating with the hydride complex, and a hydrazido intermediate can be isolated. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
